Rh-Catalyzed Aminative Dearomatization of Naphthols with Hydroxylamine-O-Sulfonic Acid (HOSA)

被引：18

作者：

Yi, Ji-Cheng ^{[1
,2
]}

Wu, Zhi-Jie ^{[1
,2
]}

You, Shu-Li ^{[1
,2
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Organ Chem, Ctr Excellence Mol Synth, State Key Lab Organometall Chem, 345 Lingling Lu, Shanghai 200032, Peoples R China

[2] Sch Phys Sci & Technol, 100 Haike Rd, Shanghai 201210, Peoples R China

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2019年 / 2019卷 / 33期

基金：

国家重点研发计划;

关键词：

Amination; Dearomatization; Homogeneous catalysis; Naphthol; Rhodium; ASYMMETRIC DEAROMATIZATION; INTRAMOLECULAR DEAROMATIZATION; OXIDATIVE DEAROMATIZATION; ARYLATIVE DEAROMATIZATION; PHENOL DEAROMATIZATION; ENANTIOSELECTIVE DEAROMATIZATION; BETA-NAPHTHOLS; BOND FORMATION; SPIROLACTONIZATION; 2-NAPHTHOLS;

D O I：

10.1002/ejoc.201900917

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient Rh-catalyzed aminative dearomatization of naphthols was achieved. In the presence of Rh-2(esp)(2) and HOSA as an inexpensive and readily available aminating reagent, a series of unprotected alpha-amino-beta-naphthalenones was afforded in good yields under mild reaction conditions. This reaction features good tolerance of functional groups and multi mmol-scale reaction.

引用

页码：5736 / 5739

页数：4

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