Growth and characterization of Zn-ZnO core-shell polygon prismatic nanocrystals on Si

被引:16
|
作者
Lin, CC [1 ]
Liu, KH [1 ]
Chen, SY [1 ]
机构
[1] Natl Chiao Tung Univ, Dept Mat Sci & Engn, Hsinchu 300, Taiwan
关键词
photo luminescence; nanocrystals; Zn; ZnOx;
D O I
10.1016/j.jcrysgro.2004.05.064
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
Zn precursor synthesized from Zn(ClO4)(2) Solution was used as nucleation seeds for the growth of Zn polygon prismatic nanocrystals on silicon via a thermal vapor transport at low temperatures of 150-400degreesC (substrate) in Ar atmosphere. Depending on different reaction temperature and atmosphere, Zn-ZnO core-shell polygon prismatic nanocrystals with a dimension from nanometer to micrometer can be developed as evidenced from high-resolution transmission electron microscopy and auger nanoprobe electron spectroscopy analysis. The Zn-ZnO polygon prismatic structure shows weak UV emission and strong deep-level emission. However, photoluminescence properties and crystallization of Zn-ZnO prismatic nanocrystals could be improved by suitable post-treatment. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:425 / 431
页数:7
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