RbBa2(N3)5:: a new ternary azide

被引：1
|
作者：
Vajenine, Grigori V.
机构：
[1] Max Planck Inst Festkorperforsch, D-70569 Stuttgart, Germany
[2] Univ Stuttgart, Inst Anorgan Chem, F-70569 Stuttgart, Germany
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2006年 / 62卷
关键词：
D O I：
10.1107/S0108270106033981
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Rubidium dibarium penta-azide, RbBa2(N-3)(5), was prepared from an aqueous solution of the binary azides at room temperature. It crystallizes in the monoclinic system (space group P2/n). Two central atoms of azide groups occupy the 2c ((1) over bar) and 2b ((1) over bar) positions, another azide group lies completely on a twofold axis (2f), while Rb atoms are situated in 2e (2) positions. The crystal structure of RbBa2(N-3)(5) can be regarded as a distorted AlB2-type arrangement of the metal atoms, with the azide groups occupying the voids between the cations. This results in coordination numbers of 8 (Rb) and 10 (Ba). The N-N distances are in the range 1.169 (8)-1.190 (5) angstrom, typical for the azide group.
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页码：I85 / I87
页数：3
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