Magnetic and catalytic properties of inverse spinel CuFe2O4 nanoparticles

被引:74
|
作者
Anandan, S. [1 ,2 ]
Selvamani, T. [1 ]
Prasad, G. Guru [1 ]
Asiri, A. M. [3 ]
Wu, J. J. [2 ]
机构
[1] Natl Inst Technol, Dept Chem, Nanomat & Solar Energy Convers Lab, Tiruchirappalli 620015, India
[2] Feng Chia Univ, Dept Environm Engn & Sci, Taichung 407, Taiwan
[3] King Abdulaziz Univ, Ctr Excellence Adv Mat Res, POB 80203, Jeddah 21413, Saudi Arabia
关键词
Ferrites; Magnetic materials; Mossbauer spectroscopy; Catalytic properties; THIN-FILMS; FERRITE; POWDER;
D O I
10.1016/j.jmmm.2017.02.026
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In this research, inverse spinel copper ferrite nanoparticles (CuFe2O4 NPs) were synthesized via citrate-nitrate combustion method. The crystal structure, particle size, morphology and magnetic studies were investigated using various instrumental tools to illustrate the formation of the inverse spinel structure. Mossbauer spectrometry identified Fe is located both in the tetrahedral and octahedral site in the ratio (40:60) and the observed magnetic parameters values such as saturation magnetization (M-s = 20.62 emu g (1)), remnant magnetization (M-r = 11.66 emu g (1)) and coercivity (H-c = 63.1 mTesla) revealed that the synthesized CuFe2O4 NPs have a typical ferromagnetic behaviour. Also tested CuFe2O4 nanoparticles as a photocatalyst for the decolourisation of methylene blue (MB) in the presence of peroxydisulphate as the oxidant. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码:437 / 443
页数:7
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