Synthesis and structure of a new copper diphosphonate with a ladder-like chain structure

被引：0
|
作者：
Song, HH [1 ]
Zheng, LM [1 ]
Xin, XQ [1 ]
机构：
[1] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
来源：
CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2002年 / 18卷 / 09期
关键词：
copper diphosphonate; crystal structure; 1-hydroxyethylidenediphosphonate;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
In this paper we describe a new copper diphosphonate compound [NH2 (C2H4) 2NH2] Cu-3 (hedp)2(H2O) 4 (hedp = 1-hydroxyethylidenediphosphonate, CH3C(OH)(PO3)(2)) synthesized under hydrothermal conditions. Single crystal structure determination reveals that the compound contains anionic ladder-like chains of [Cu-3(hedp)(2)(H2O)(4)](n) which are linked by moderately strong inter-chain hydrogen bonds, forming a supramolecular layer. The protonated piperazine fill the spaces between the layers.
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收藏
页码：941 / 944
页数：4
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