Highly dispersible polymer-coated silver Nanoparticles

被引:35
|
作者
Vasiliev, Aleksey N. [1 ]
Gulliver, Eric A. [2 ]
Khinast, Johannes G. [3 ]
Riman, Richard E. [1 ]
机构
[1] Rutgers State Univ, Dept Mat Sci & Engn, Piscataway, NJ 08854 USA
[2] Ferro Inc, Elect Mat Div, S Plainfield, NJ 07080 USA
[3] Rutgers State Univ, Dept Chem & Biochem Engn, Piscataway, NJ 08854 USA
来源
SURFACE & COATINGS TECHNOLOGY | 2009年 / 203卷 / 19期
关键词
Silver; Nanoparticles; Thiolation; Polymer; Coating; Dispersibility; SELF-ASSEMBLED MONOLAYERS; ALKANETHIOLATE MONOLAYERS; SURFACE; GOLD; ACID; CHEMISTRY; AG(111); ELECTROCHEMISTRY; SPECTROSCOPY; ADSORPTION;
D O I
10.1016/j.surfcoat.2009.02.019
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Highly dispersible silver nano-material was obtained by surface functionalization of silver nanoparticles with polylactic acid. The thiolation method was used for attaching carboxyl groups to the silver surface by treatment with 3-mercaptopropionic acid. The carboxyl groups were further activated by diisopropylcarbodiimide and reacted with polylactic acid. The functionalized nanoparticles contained 1.88 wt.% organic phase. While the as-received silver nanopowder exhibited poor colloidal stability in tetrahydrofuran, particle size analysis revealed that the functionalized material displayed high dispersibility, in this solvent. (c) 2009 Published by Elsevier B.V.
引用
收藏
页码:2841 / 2844
页数:4
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