Esterification of Acetic Acid and Ethanol in a Flow-Through Membrane Reactor Coupled with Pervaporation

被引：21
|
作者：
Guo, Shiwei [1 ]
He, Benqiao [1 ]
Li, Jianxin [1 ]
Zhao, Quan [1 ]
Cheng, Yu [1 ]
机构：
[1] Tianjin Polytech Univ, Sch Mat Sci & Engn, State Key Lab Hollow Fiber Membrane Mat & Proc, Tianjin 300387, Peoples R China
来源：
CHEMICAL ENGINEERING & TECHNOLOGY | 2014年 / 37卷 / 03期
基金：
中国国家自然科学基金;
关键词：
Composite catalytic membrane; Esterification; Ethyl acetate; Pervaporation; CATALYTIC MEMBRANE; ETHYL-ACETATE; ASSISTED ESTERIFICATION; LIQUID-PHASE; BIODIESEL; ZEOLITES; OIL;
D O I：
10.1002/ceat.201300467
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
The esterification of acetic acid is an important industrial process for the synthesis of ethyl acetate. A membrane reactor with a sulfonated polyethersulfone/polyethersulfone/non-woven fabrics composite catalytic coupled with a poly(vinyl alcohol) pervaporation membrane was applied in continuous esterification of ethanol with acetic acid in a flow-through mode. High equilibrium conversion was obtained for esterification in a closed-loop mode. For the pervaporation-assisted esterification in this mode, the experimental conversion was very close to the theoretical value.
引用
收藏
页码：478 / 482
页数：5
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