Chemical transformations of methane in trifluoroacetic acid

被引：1
|
作者：
Vishnetskaya, M. V. [1 ]
Svichkarev, O. M. [1 ]
Budynina, E. M. [2 ]
Mel'nikov, M. Ya. [2 ]
机构：
[1] Gubkin State Univ Oil & Gas, Moscow 119991, Russia
[2] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119991, Russia
来源：
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A | 2013年 / 87卷 / 12期
基金：
俄罗斯基础研究基金会;
关键词：
molecular oxygen; activation; methane; C-C bond; trifluoroacetic acid; ACETIC-ACID; SATURATED-HYDROCARBONS; CARBOXYLATION REACTION; MILD CONDITIONS; VANADIUM COMPLEXES; CATALYTIC-SYSTEM; ONE-STEP; CO; CONVERSION; OXIDATION;
D O I：
10.1134/S0036024413120261
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The reaction of methane conversion in anhydrous trifluoroacetic acid (TFA) is shown to take place at room temperature and atmospheric pressure and to result in the formation of a resinous product. Signals of ions with molecular weights of 684 and 700 are observed in MALDI-TOF spectra of the dry residue of methane conversion products.
引用
收藏
页码：2001 / 2004
页数：4
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