Kinetics of gas phase reactions of OH and Cl with aromatic aldehydes

被引：20
|
作者：
Thiault, G [1 ]
Mellouki, A [1 ]
Le Bras, G [1 ]
机构：
[1] CNRS, LCSR, F-45071 Orleans 2, France
来源：
PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2002年 / 4卷 / 11期
关键词：
D O I：
10.1039/b200609j
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Rate constants for the OH and Cl reactions with four aromatic aldehydes have been determined at 298 +/- 2K and atmospheric pressure using a relative rate method. The measured rate constants are (in cm(3) molecule(-1) s(-1)): [GRAPHICS] This work provides the first measurements for the OH and Cl reaction rate constants with tolualdehydes. The results obtained are presented and compared with the previous measurements only available for benzaldehyde. The atmospheric implications are also discussed.
引用
收藏
页码：2194 / 2199
页数：6
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