A Novel Heterometallic Cluster-Based Coordinational Polymer with 2-[Bis-(2-hydroxy-ethyl)-Amino]-Ethanesulfonic Acid: Synthesis and Crystal Structure

被引：12
|
作者：
Zhang, Chun Lian [1 ]
Jiang, Xi Fu [1 ]
Yang, Li [1 ]
Zhang, Shu Hua [1 ]
Shi, Shao Ming [2 ]
机构：
[1] Guilin Univ Technol, Coll Chem & Bioengn, Guilin 541004, Peoples R China
[2] Liu Zhou Vocat & Tech Coll, Liuzhou 545006, Guangxi, Peoples R China
来源：
JOURNAL OF CLUSTER SCIENCE | 2014年 / 25卷 / 02期
关键词：
Coordination polymer; Crystal structure; Chiral synthesis; METAL-ORGANIC FRAMEWORK; COPPER(II) COMPLEX; LIGAND; THERMOANALYSIS;
D O I：
10.1007/s10876-013-0624-x
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A rare heterometallic cluster-based polymer [Cu-4(Hbhea)(4)(mu (2)-OCH3) K(CH3OH))] (n) center dot(H2O) (n) (1) (H(3)bhea = 2-[bis-(2-hydroxy-ethyl)-amino]-ethanesulfonic acid), has been synthesized and structurally determined by single crystal X-ray diffraction, elemental analysis. Crystallographic unit of 1 consists of four Cu(II), four Hbhea ligands, one methanol molecule, one methanol anion, one K ion and one crystal lattice water and formed anion cluster [Cu-4(Hbhea)(4)(CH3O)](-) which further constructed a 3-D polymer by linking the six-coordination K ions.
引用
收藏
页码：459 / 466
页数：8
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