Alkali-activated binders based on ground granulated blast furnace slag and phosphogypsum

被引:61
|
作者
Gijbels, Katrijn [1 ]
Lacobescu, Remus Ion [2 ]
Pontikes, Yiannis [2 ]
Schreurs, Sonja [1 ]
Schroeyers, Wouter [1 ]
机构
[1] Hasselt Univ, CMK, Nucl Technol Ctr, Agoralaan, Gebouw H, B-3590 Diepenbeek, Belgium
[2] Katholieke Univ Leuven, Dept Mat Engn, Kasteelpk Arenberg 44, B-4001 Leuven, Belgium
关键词
Super-sulphated cement; Alkali-activated binder; Ground granulated blast furnace slag; Phosphogypsum; Hydration; Building material; C-S-H; CALCIUM SILICATE HYDRATE; REACTION-KINETICS; SUPERSULFATED CEMENT; SPECTROSCOPY; MECHANISMS; PHASE; FTIR; GEL; IMMOBILIZATION;
D O I
10.1016/j.conbuildmat.2019.04.194
中图分类号
TU [建筑科学];
学科分类号
0813 ;
摘要
The effect of phosphogypsum (PG) in alkali-activated ground granulated blast furnace slag (GGBFS) on the reactivity, strength development and final matrix properties was investigated, as a function of alkali activator. The results were compared with alkali-activated reference samples from GGBFS. PG completely dissolves and takes part in solid reaction product formation. Upon PG incorporation, portlandite and ettringite are initially formed after dissolution. The hardened binder consists mainly of amorphous hydration products, intermixed with thenardite and minor amounts of secondary gypsum and merwinite. PG incorporation resulted in faster initial and delayed final setting time, while it enhanced the compressive strength and amorphous phase development when sodium hydroxide was used. PG gave rise to a decrease of Al/Si and Ca/Si ratios in the C-A-S-H gels and a higher polymerized network. (C) 2019 Elsevier Ltd. All rights reserved.
引用
收藏
页码:371 / 380
页数:10
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