Linear alkaline earth metal phosphinate coordination polymers: synthesis and structural characterization

被引：7

作者：

Rood, Jeffrey A. ^{[1
]}

Huttenstine, Ashley L. ^{[1
]}

Schmidt, Zachery A. ^{[1
]}

White, Michael R. ^{[1
]}

Oliver, Allen G. ^{[2
]}

机构：

[1] Elizabethtown Coll, Dept Chem & Biochem, Elizabethtown, PA 17022 USA

[2] Univ Notre Dame, Dept Chem & Biochem, Notre Dame, IN 46556 USA

来源：

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS | 2014年 / 70卷

基金：

美国国家科学基金会;

关键词：

INORGANIC-ORGANIC HYBRIDS; X-RAY CHARACTERIZATION; P; P'-DIPHENYLMETHYLENEDIPHOSPHINIC ACID; CRYSTAL-STRUCTURES; CALCIUM FORMATE; GUEST-EXCHANGE; FRAMEWORK; COBALT(II); COMPLEX; ABSORPTION;

D O I：

10.1107/S2052520614004247

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of alkaline earth metal salts with diphenylphosphinic acid in dimethylformamide solvent afforded four coordination polymers: [Mg-3(O2PPh2)(6)(DMF)(2)]center dot 2DMF (I), [Ca(O2PPh2)(2)-(DMF)(2)] (II), [Sr(O2PPh2)(2)(DMF)(2)] (III) and [Ba(O2PPh2)(2)-(DMF)(2)] (IV) (where DMF is N,N-dimethylformamide). Single-crystal X-ray diffraction revealed that all four compounds produce linear chain structures in the solid state, with the Ca, Sr and Ba forming isostructural crystals. The bulk materials were characterized by FT-IR and H-1 NMR spectroscopy and elemental analyses.

引用

页码：602 / 607

页数：6

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