Novel phosphorus-containing poly(ether sulfone)s and their blends with an epoxy resin:: Thermal decomposition and fire retardancy

被引：56
|
作者：
Braun, Ulrike
Knoll, Uta
Schartel, Bernhard
Hoffmann, Thorsten
Pospiech, Doris
Artner, Johannes
Ciesielski, Michael
Doering, Manfred
Perez-Gratero, Raul
Sandler, Jan K. W.
Altstaedt, Volker
机构：
[1] BAM, Fed Inst Mat Res & Testing, D-12205 Berlin, Germany
[2] Leibniz Inst Polymer Res Dresden, D-01069 Dresden, Germany
[3] Res Ctr Karlsruhe GmbH, Inst Tech Chem, D-76021 Karlsruhe, Germany
[4] Univ Bayreuth, D-95440 Bayreuth, Germany
来源：
MACROMOLECULAR CHEMISTRY AND PHYSICS | 2006年 / 207卷 / 16期
关键词：
epoxy; flame retardance; high performance polymers; polysulfones; thermogravimetric analysis (TGA);
D O I：
10.1002/macp.200600182
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The decomposition of novel phosphorus-containing poly(oxyphenylene-sulfonyl-phenylene-oxydiphenyl phenylene phosphine oxide) (PSU_I), 2,5-dihydroxy-1-biphenylene-phosphine oxide based polysulfone (PSU_II), poly(sulfonyl-diphenylphenylene phosphonate) (PSU_P) and bisphenol A-based polysulfone (PSU) is studied. The influence of the chemical structure, charring and phosphorus release is discussed based on the mass loss, kinetics and products. The pyrolysis and fire behaviour of blends with epoxy resin (EP) are studied. For EP-PSU_II, phosphorus initiates water elimination and changes the decomposition pathway of ER The fire behaviour of EP-PSU shows some improvements, whereas the heat release rate is crucially reduced for EP-PSU_II due to simultaneous char formation and flame inhibition.
引用
收藏
页码：1501 / 1514
页数：14
相关论文
共 50 条
  • [1] Flame retardancy study on phosphorus-containing epoxy resin synthesized by the reaction of DOPO and the diglycidyl ether of bisphenol A
    Hao, Jian-Wei
    Xiong, Yan-Bing
    Zhang, Tao
    [J]. Beijing Ligong Daxue Xuebao/Transaction of Beijing Institute of Technology, 2006, 26 (03): : 279 - 282
  • [2] Effect of phosphorus-containing flame retardants on flame retardancy and thermal stability of tetrafunctional epoxy resin
    Zhang, Chunling
    Pan, Miao
    Qu, Lijie
    Sun, Guoen
    [J]. POLYMERS FOR ADVANCED TECHNOLOGIES, 2015, 26 (12) : 1531 - 1536
  • [3] Synthesis and characterization of a phosphorus-containing poly(ether ether ketone ketone sulfone)
    Sun Hao
    Chen Xiaoting
    Tang Xudong
    Wang Chunying
    [J]. ACTA POLYMERICA SINICA, 2007, (01) : 90 - 92
  • [4] Flame retardancy of epoxy resin with phosphorus-containing reactive amine and clay minerals
    Toldy, A.
    Toth, N.
    Anna, P.
    Keglevich, Gy.
    Kiss, K.
    Marosi, Gy.
    [J]. POLYMERS FOR ADVANCED TECHNOLOGIES, 2006, 17 (9-10) : 778 - 781
  • [5] Engineering phosphorus-containing lignin for epoxy biocomposites with enhanced thermal stability, fire retardancy and mechanical properties
    Zhang, Anlin
    Zhang, Jianzhong
    Liu, Lina
    Dai, Jinfeng
    Lu, Xinyu
    Huo, Siqi
    Hong, Min
    Liu, Xiaohuan
    Lynch, Mark
    Zeng, Xuesen
    Burey, Paulomi
    Song, Pingan
    [J]. JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY, 2023, 167 : 82 - 93
  • [6] Synthesis of a novel phosphorus-containing dicyclopentadiene novolac hardener and its cured epoxy resin with improved thermal stability and flame retardancy
    Yang J.-W.
    Wang Z.-Z.
    Liu L.
    [J]. Wang, Zheng-Zhou (zwang@tongji.edu.cn), 1600, John Wiley and Sons Inc (134):
  • [7] Synthesis of a novel phosphorus-containing dicyclopentadiene novolac hardener and its cured epoxy resin with improved thermal stability and flame retardancy
    Yang, Jian-Wei
    Wang, Zheng-Zhou
    Liu, Lei
    [J]. JOURNAL OF APPLIED POLYMER SCIENCE, 2017, 134 (11)
  • [8] The Study on Poly(ether sulfone) Modified Cyanate Ester Resin and Epoxy Resin Cocuring Blends
    Zhan, Guozhu
    Hu, Sheng
    Yu, Yingfeng
    Li, Shanjun
    Tang, Xiaolin
    [J]. JOURNAL OF APPLIED POLYMER SCIENCE, 2009, 113 (01) : 60 - 70
  • [9] Study on phenolphthalein poly(ether sulfone)-modified cyanate ester resin and epoxy resin blends
    Wang, Guan
    Wang, Rongguo
    Fu, Gang
    Gao, Tangling
    Fu, Chunming
    Kuang, Hong
    Yang, Fan
    Jiao, Weicheng
    Hao, Lifeng
    Liu, Wenbo
    [J]. POLYMER ENGINEERING AND SCIENCE, 2015, 55 (11): : 2591 - 2602
  • [10] Synthesis and properties of novel phosphorus-containing poly(ether ether ketone ketone)s
    Chen, Xiao-Ting
    Sun, Hao
    Tang, Xu-Dong
    Wang, Chun-Ying
    [J]. JOURNAL OF APPLIED POLYMER SCIENCE, 2008, 110 (03) : 1304 - 1309
12345