Synthesis and Characterization of a Two-dimensional Cadmium(II) Metal Organic Framework with Fes Topology

被引：0
|
作者：
Li Huan-Huan [1 ]
Liu Li [1 ]
Ming Chun-Lun [1 ]
Cui Guang-Hua [1 ]
机构：
[1] Hebei United Univ, Coll Chem Engn, Tangshan 063009, Hebei, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2014年 / 33卷 / 07期
关键词：
Cd(II) complex; crystal structure; fluorescence property; 5-nitrobenzene-1,2,3-tricarboxylic acid; COBALT(II) COORDINATION POLYMERS; CRYSTAL-STRUCTURES; LIGANDS; ARCHITECTURES; FLUORESCENCE; COMPLEXES; ACID; NET;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new Cd(II) coordination polymer, {[Cd(Hnbta)(L)]center dot H2O}(n) (L = 1,4-bis(5,6-dimethylbenzimidazol-1-yl)butane), H(3)nbta= 5-nitrobenzene-1,2,3-tricarboxylic acid), has been hydro-thermally synthesized and characterized by elemental analyses, IR, XRPD, and single-crystal X-ray diffraction. The title compound crystallizes in the monoclinic system, space group P2(1)/n with a = 17.3056(13), b = 11.0114(9), c = 17.7484(14) angstrom, beta = 117.3640(10)degrees, V = 3003.7(4) angstrom(3), Z = 4, C31H31CdN5O9, M-r = 730.01, D-c = 1.614 g/cm(3), mu = 0.792 mm(-1) and F(000) = 1488. The cadmium(II) ions are bridged by Hnbta(2-) to generate a two-dimensional metal organic framework with fes topology. In addition, the thermal stability and fluorescence properties of the complex were also studied.
引用
收藏
页码：1050 / 1056
页数：7
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