Application of tert-Butanesulfinamide in Total Synthesis of Natural Products

被引：4
|
作者：
Li, Ying [1 ]
Ma, Zhiqiang [1 ,2 ]
Xu, Xuetao [1 ]
机构：
[1] Wuyi Univ, Sch Biotechnol & Hlth Sci, Jiangmen 529020, Guangdong, Peoples R China
[2] South China Univ Technol, Key Lab Funct Mol Engn Guangdong Prov, Sch Chem & Chem Engn, Guangzhou 510641, Peoples R China
来源：
CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2020年 / 40卷 / 12期
关键词：
tert-butanesulfinamide; chiral amine; total synthesis; CONCISE TOTAL-SYNTHESIS; ENANTIOSELECTIVE TOTAL-SYNTHESIS; EFFICIENT ASYMMETRIC-SYNTHESIS; STEREOSELECTIVE-SYNTHESIS; FORMAL SYNTHESIS; IMINES; AMINES; SYN-1,3-AMINO; INTERMEDIATE; ALKYLATION;
D O I：
10.6023/cjoc202006024
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The formation of chiral amine intermediates with chiral tert-butanesulfinamide and their applications in asymmetric natural product synthesis in recent years are summarized. tert-Butanesulfinamide has attracted wide attention from chemists because it is stable, commercially available with reasonable price, ease to use, and usually induces high diastereoselectivity in the reactions involved. This review is divided into two sections, including the addition of nucleophiles to N-tert-butanesulfinyl imines and the addition of N-tert-butanesulfinyl metalloenamines to electrophiles.
引用
收藏
页码：3991 / 4014
页数：24
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