Highly regio- and diastereoselective Cu-catalyzed hydroborylation and hydrosilylation of difluorocyclopropenes with B2pin2 and PhMe2Si-Bpin

被引：14
|
作者：
Zhao, Xianghu [1 ]
Xu, Sixue [1 ]
He, Jingjing [1 ]
Zhou, Yao [1 ]
Cao, Song [1 ]
机构：
[1] ECUST, Sch Pharm, Shanghai Key Lab Chem Biol, Shanghai 200237, Peoples R China
来源：
ORGANIC CHEMISTRY FRONTIERS | 2019年 / 6卷 / 14期
基金：
中国国家自然科学基金;
关键词：
ENANTIOSELECTIVE HYDROBORATION; GEM-DIFLUOROCYCLOPROPANATION; NUCLEOPHILIC SILICON; BUILDING-BLOCKS; BETA-BORATION; H BORYLATION; ONE-POT; CYCLOPROPENES; CYCLOPROPANATION; ACTIVATION;
D O I：
10.1039/c9qo00580c
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An efficient synthetic method for preparing trans-difluorocyclopropyl boronates and trans-difluorocyclopropyl silanes was easily achieved through a copper-catalyzed hydroborylation and hydrosilylation of difluorocyclopropenes with bis(pinacolato)diboron and silylboronate, respectively.
引用
收藏
页码：2539 / 2543
页数：5
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