Synthesis of High-Purity Imidazolium Tetrafluoroborates and Bis(oxalato)borates

被引：5
|
作者：
Schmitz, Paulo [1 ,2 ]
Jakelski, Rene [1 ,2 ]
Jalkanen, Kirsi [1 ,2 ]
Winter, Martin [1 ,2 ,3 ]
Bieker, Peter [1 ,2 ]
机构：
[1] Univ Munster, Inst Phys Chem, Corrensstr 28-30, D-48149 Munster, Germany
[2] Univ Munster, MEET Battery Res Ctr, Corrensstr 46, D-48149 Munster, Germany
[3] Forschungszentrum Julich, Helmholtz Inst Munster, IEK 12, Corrensstr 46, D-48149 Munster, Germany
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2017年 / 23卷 / 10期
关键词：
borates; flashpoints; ionic liquids; room-temperature molten salts; synthetic methods; TEMPERATURE IONIC LIQUIDS; LITHIUM BATTERIES; ELECTROCHEMICAL PROPERTIES; ELECTROLYTES; BEHAVIOR; ANIONS; PERFORMANCE; CORROSION; CHLORIDE; CATIONS;
D O I：
10.1002/chem.201604461
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The synthesis and purification of imidazolium-based ionic liquids (ILs) with boron-containing anions is reported. The scope was the optimization of the meta thesis reaction and on the purification of the synthesized ILs. It was possible to reduce the reaction and purification times, to avoid the use of acetonitrile as processing solvent, and to increase the yield compared to the known procedure for [BOB](-) anion-containing ILs. Furthermore, to the best of our knowledge the flashpoints of the ILs could be determined for the first time by the continuously closed-cup flashpoint (CCCFP) method.
引用
收藏
页码：2261 / 2264
页数：4
相关论文
共 50 条
  • [1] BORON COMPLEXES WITH DICARBOXYLIC-ACIDS - BIS(OXALATO)BORATES AND BIS(MALONATO)BORATES
    BESSLER, E
    WEIDLEIN, J
    [J]. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1982, 37 (08): : 1020 - 1025
  • [2] Synthesis of high-purity trialkylgermanethiols
    M. G. Voronkov
    R. G. Mirskov
    S. N. Adamovich
    [J]. Russian Journal of Applied Chemistry, 2007, 80 : 338 - 338
  • [3] Synthesis of high-purity trialkylgermanethiols
    Voronkov, M.G.
    Mirskov, R.G.
    Adamovich, S.N.
    [J]. Russian Journal of Applied Chemistry, 2007, 80 (02):
  • [4] Synthesis of high-purity heptamethylchlorocyclotetrasiloxane
    Martynova, TN
    Voronkov, MG
    [J]. RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 2000, 73 (05) : 921 - 922
  • [5] Synthesis of high-purity alkylsilanes
    D. V. Sidorov
    P. A. Storozhenko
    O. G. Shutova
    B. E. Kozhevnikov
    [J]. Theoretical Foundations of Chemical Engineering, 2007, 41 : 668 - 670
  • [6] Synthesis of high-purity alkylsilanes
    Sidorov, D. V.
    Storozhenko, P. A.
    Shutova, O. G.
    Kozhevnikov, B. E.
    [J]. THEORETICAL FOUNDATIONS OF CHEMICAL ENGINEERING, 2007, 41 (05) : 668 - 670
  • [7] Synthesis of high-purity trialkylgermanethiols
    Voronkov, M. G.
    Mirskov, R. G.
    Adamovich, S. N.
    [J]. RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 2007, 80 (02) : 338 - 338
  • [8] SYNTHESIS, STRUCTURAL AND MAGNETIC STUDIES OF IMIDAZOLIUM BIS(OXALATO)CUPRATE(II)
    CHATTOPADHYAY, SK
    MAK, TCW
    LUO, BS
    THOMPSON, LK
    RANA, A
    GHOSH, S
    [J]. POLYHEDRON, 1995, 14 (23-24) : 3661 - 3667
  • [9] An improved synthesis of high-purity felodipine
    Yiu, SH
    Knaus, EE
    [J]. ORGANIC PREPARATIONS AND PROCEDURES INTERNATIONAL, 1996, 28 (01) : 91 - 95
  • [10] SYNTHESIS OF HIGH-PURITY THALLIUM MONOIODIDE
    GOSPODINOV, GG
    OIKOVA, TG
    [J]. JOURNAL OF APPLIED CHEMISTRY OF THE USSR, 1981, 54 (07): : 1348 - 1349
12345