Rheology of polymer melts and concentrated solutions

被引:18
|
作者
Marrucci, G [1 ]
Greco, F [1 ]
Ianniruberto, G [1 ]
机构
[1] Univ Naples Federico II, Dipartimento Ingn Chim, I-80125 Naples, Italy
关键词
rheology; entangled polymers; long branching; viscoelasticity; convective constraint release;
D O I
10.1016/S1359-0294(99)90002-X
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The basic concepts of entangled polymer dynamics, like that of 'tube' of constraints and of 'reptation', have not yet exhausted their momentum. Further progress has taken place recently with detailed calculations of tube length fluctuations and constraint release, not only for branched polymers but also for linear ones. Progress in the non-linear range has occurred with the concept of convective constraint release and, for branched polymers, with the so-called 'pom-pom' model. Lack of complete agreement between theory and experiments stimulates work to proceed along various lines. (C) 1999 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:283 / 287
页数:5
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