Balancing framework densification with charged, halogen-bonded-π-conjugated linkages:: [PPh4]2{[E-TTF-I2][Re6Se8(CN)6]} versus [PPh4]2[EDT-TTF-I]2{[EDT-TTF-I][Re6Se8(CN)6]}

被引：36
|
作者：
Ranganathan, Anupama
El-Ghayoury, Abdelkrim
Meziere, Cecile
Harte, Etienne
Clerac, Rodolphe
Batail, Patrick
机构：
[1] Univ Angers, UMR 6200 CNRS, Lab Chim Ingn Mol & Mat Angers, F-49045 Angers, France
[2] Ctr Rech Paul Pascal, CNRS, UPR 8641, F-33600 Pessac, France
来源：
CHEMICAL COMMUNICATIONS | 2006年 / 27期
关键词：
D O I：
10.1039/b600159a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The ionic character of a set of two redox linkages and strong, directional halogen bonding at the organic - inorganic interface compromise to produce two materials sharing a common two-dimensional net, eventually extended in a third dimension, although two of the six symmetrical halogen bond acceptors ultimately remain uninvolved as a result of charge densification.
引用
收藏
页码：2878 / 2880
页数：3
相关论文
共 50 条
  • [1] Robust Dirac-Cone Band Structure in the Molecular Kagome Compound (EDT-TTF-CONH2)6[Re6Se8(CN)6]
    Carlsson, Sandra
    Zorina, Leokadiya
    Allan, David R.
    Attfield, J. Paul
    Canadell, Enric
    Batail, Patrick
    [J]. INORGANIC CHEMISTRY, 2013, 52 (06) : 3326 - 3333
  • [2] Interdependence of redox state, hydrogen bonding, anion recognition and charge partition in crystals of (EDT-TTF-CONHMe)6 [Re6Se8(CN)6] (CH3CN)2(CH2Cl2)
    Baudron, SA
    Batail, P
    Rovira, C
    Canadell, E
    Clérac, R
    [J]. CHEMICAL COMMUNICATIONS, 2003, (15) : 1820 - 1821
  • [3] Cyclic polyselenidoarsenates(III) and polyselenidoantimonates(III):: PPh4[Se5AsSe], PPh4[AsSe6-xSx], (PPh4)2[As2Se6]•2CH3CN, and (PPh4)2[Se6SbSe]2
    Czado, W
    Muller, U
    [J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1998, 624 (02): : 239 - 243
  • [4] (EDT-TTF-CONH2)6[Re6Se8(CN)6], a metallic Kagome-type organic-inorganic hybrid compound:: Electronic instability, molecular motion, and charge localization
    Baudron, SA
    Batail, P
    Coulon, C
    Clérac, R
    Canadell, E
    Laukhin, V
    Melzi, R
    Wzietek, P
    Jerome, D
    Auban-Senzier, P
    Ravy, S
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (33) : 11785 - 11797
  • [5] Structure and catalytic activity of a hexarhenium cluster-supported copper cubanes [{Cu4(μ-OH)4(NH3)7}2{Re6Se8(CN)6}][Re6Se8(CN)6]•2H2O
    Xu, Li
    Kim, Youngmee
    Kim, Sung-Jin
    Kim, Hee Jin
    Kim, Cheal
    [J]. INORGANIC CHEMISTRY COMMUNICATIONS, 2007, 10 (05) : 586 - 589
  • [6] Crystal structure of Tl4[Re6Se8(CN)6]•1.5H2O
    Virovets, AV
    Naumov, NG
    Naumov, DY
    Howard, JAK
    Fedorov, VE
    [J]. JOURNAL OF STRUCTURAL CHEMISTRY, 2000, 41 (05) : 895 - 900
  • [7] Crystal Structure of Tl4[Re6Se8(CN)6]·1.5H2O
    A. V. Virovets
    N. G. Naumov
    D. Yu. Naumov
    J. A. K. Howard
    V. E. Fedorov
    [J]. Journal of Structural Chemistry, 2000, 41 : 895 - 900
  • [8] Synthesis, structure, and 77Se NMR study of the (PPh4)2[Re6Se6Br8] complex
    S. S. Yarovoi
    S. F. Solodovnikov
    S. V. Tkachev
    Yu. V. Mironov
    V. E. Fedorov
    [J]. Russian Chemical Bulletin, 2003, 52 : 68 - 72
  • [9] Synthesis, structure, and 77Se NMR study of the (PPh4)2[Re6Se6Br8] complex
    Yarovoi, SS
    Solodovnikov, SF
    Tkachev, SV
    Mironov, YV
    Fedorov, VE
    [J]. RUSSIAN CHEMICAL BULLETIN, 2003, 52 (01) : 68 - 72
  • [10] Synthesis and Structure of Co2[Re6Se8(CN)6]⋅12H2O
    N. G. Naumov
    M. N. Sokolov
    H. Imoto
    T. Saito
    V. E. Fedorov
    [J]. Journal of Structural Chemistry, 2001, 42 : 326 - 330
12345