Glucose, cellobiose, lactose and raffinose used as chiral stationary phases in HPLC

被引：4

作者：

Wang, Jian Yu ^{[1
]}

Zhao, Feng ^{[1
]}

Zhang, Mei ^{[1
]}

Peng, Ya ^{[1
]}

Yuan, Li Ming ^{[1
]}

机构：

[1] Yunnan Normal Univ, Dept Chem, Kunming 650092, Peoples R China

来源：

CHINESE CHEMICAL LETTERS | 2008年 / 19卷 / 10期

关键词：

Oligosaccharides; Chiral stationary phase; HPLC;

D O I：

10.1016/j.cclet.2008.07.003

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This paper presents the enantioseparation using glucose, cellobiose, lactose and raffinose as chiral selector bonded to silica gel via an arm in HPLC. Surprisingly, they also possess high enantioseparation selectivity, may be used in normal-phase and reversed-phase mode, and there is a big chiral discriminating complementary. This work indicates that oligosaccharides could soon become very attractive as a new class of chiral stationary phase for HPLC. (C) 2008 Li Ming Yuan. Published by Elsevier B. V. on behalf of Chinese Chemical Society. All rights reserved.

引用

页码：1248 / 1251

页数：4

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