Iridium(I) hydroxides in catalysis: rearrangement of allylic alcohols to ketones

被引：19
|
作者：
Nelson, David J. [1 ]
Fernandez-Salas, Jose A. [1 ]
Truscott, Byron J. [1 ]
Nolan, Steven P. [1 ]
机构：
[1] Univ St Andrews, EaStCHEM Sch Chem, North Haugh KY16 9ST, Fife, Scotland
来源：
ORGANIC & BIOMOLECULAR CHEMISTRY | 2014年 / 12卷 / 34期
基金：
英国工程与自然科学研究理事会;
关键词：
ISOMERIZATION;
D O I：
10.1039/c4ob01428f
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The iridium(I) hydroxide complex [Ir(OH)(COD)((IPr)-Pr-i)] has been shown to be a competent catalyst for the rearrangement of allylic alcohols to ketones. Reactions proceed in short reaction times (1-1.5 h) with microwave heating, in the absence of additives.
引用
收藏
页码：6672 / 6676
页数：5
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