Facile synthesis of brownmillerite-type oxides Ba2In2-xMnxO5+x through a microwave-assisted process

被引：8

作者：

Jiang, Peng ^{[1
]}

Xiao, Ting ^{[1
]}

Zhou, Yuncheng ^{[1
]}

Kuang, Jianlei ^{[1
]}

Wang, Qi ^{[1
]}

Cao, Wenbin ^{[1
]}

机构：

[1] Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing 100083, Peoples R China

来源：

SOLID STATE SCIENCES | 2017年 / 65卷

基金：

中国国家自然科学基金;

关键词：

Microwave synthesis; Brownmillerite-type oxides; Turquoise and green color pigments; BA2IN2O5; CONDUCTIVITY; IRRADIATION; MN5+;

D O I：

10.1016/j.solidstatesciences.2016.12.019

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Brownmillerite-type oxides Ba2In2-xMnxO5+x {(0 <= x <= 0.6) samples showing intense turquoise to green color were synthesized through a novel microwave assisted rapid sintering method. The properties of as synthesized samples were compared with samples prepared by previously reported solid state reaction by X-ray diffraction, scanning electronic microscopy, UV-visible absorbance spectra and X-ray photoelectron spectroscopy. The X-ray diffraction patterns showed that the structure symmetry converts from orthorhombic to cubic with the increase in Mn content. And UV-visible absorbance spectra revealed that the color is tuned from turquoise to green color by manganese doping. In the as-synthesized samples, manganese is showing Mn5+ according to the X-ray photoelectron spectroscopy results. (C) 2016 Elsevier Masson SAS. All rights reserved.

引用

页码：1 / 5

页数：5

共 50 条

[1] Intense Turquoise and Green Colors in Brownmillerite-Type Oxides Based on Mn5+ in Ba2In2-xMnxO5+x
Jiang, Peng
Li, Jun
Ozarowski, A.
Sleight, Arthur W.
Subramanian, M. A.
[J]. INORGANIC CHEMISTRY, 2013, 52 (03) : 1349 - 1357
[2] Synthesis and optical properties of turquoise- and green-colored brownmillerite-type Ba2In2−x−yMnxAlyO5+x codoped with manganese and aluminum
Peng Jiang
Wen-hui Yang
Yun-cheng Zhou
Jian-lei Kuang
Yong Li
Ting Xiao
[J]. International Journal of Minerals, Metallurgy, and Materials, 2016, 23 : 1346 - 1351
[3] Solution combustion synthesis of Brownmillerite-type Ca2AlMnO5 as an oxygen storage material
Nomura, Takahiro
Zhu, Chunyu
Sheng, Nan
Murai, Ryota
Akiyama, Tomohiro
[J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2015, 646 : 900 - 905
[4] Microwave-assisted facile synthesis of 2-substituted 2-imidazolines
Pathan, Mohsin Y.
Paike, Vijaykumar V.
Pachmase, Pandurang R.
More, Sandeep P.
Ardhapure, Suresh S.
Pawar, Rajendra P.
[J]. ARKIVOC, 2006, : 205 - 210
[5] Solution combustion synthesis of Brownmillerite-type Ca2AlMnO5 as an oxygen storage material
20152801010705
[J]. Nomura, Takahiro (nms-tropy@eng.hokudai.ac.jp), 1600, Elsevier Ltd (646):
[6] Synthesis and optical properties of turquoise- and green-colored brownmillerite-type Ba2In2-x-y Mn x Al y O5+x codoped with manganese and aluminum
Jiang, Peng
Yang, Wen-hui
Zhou, Yun-cheng
Kuang, Jian-lei
Li, Yong
Xiao, Ting
[J]. INTERNATIONAL JOURNAL OF MINERALS METALLURGY AND MATERIALS, 2016, 23 (11) : 1346 - 1351
[7] Facile microwave-assisted hydrothermal synthesis of TiO2 nanotubes
Cui, L.
Hui, K. N.
Hui, K. S.
Lee, S. K.
Zhou, W.
Wan, Z. P.
Chi-Nhan Ha Thuc
[J]. MATERIALS LETTERS, 2012, 75 : 175 - 178
[8] PROGRESSIVE REDUCTION OF BARYUM FERRITE BA2FE2O5 AND STUDY OF APPEARING PHASES BA2FE2O5-2X OF BROWNMILLERITE-TYPE STRUCTURE AND BA7FE4O13
NEU, P
ZANNE, M
GERARDIN, R
GLEITZER, C
[J]. ANNALES DE CHIMIE-SCIENCE DES MATERIAUX, 1981, 6 (06): : 525 - 534
[9] Facile synthesis of high quality TiO2 nanocrystals in ionic liquid via a microwave-assisted process
Ding, Kunlun
Miao, Zhenjiang
Liu, Zhimin
Zhang, Zhaofu
Han, Buxing
An, Guimin
Miao, Shiding
Xie, Yun
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (20) : 6362 - +
[10] Facile synthesis of FeAlPO-5 molecular sieve in eutectic mixture via a microwave-assisted process
Zhao, Xinhong
Wang, Hua
Dong, Baifeng
Sun, Zhongpeng
Li, Guixian
Wang, Xiaolai
[J]. MICROPOROUS AND MESOPOROUS MATERIALS, 2012, 151 : 56 - 63

← 1 2 3 4 5 →