Synthesis of D-galactofuranosyl-containing C-disaccharides

被引:11
|
作者
Kovensky, J
Burrieza, D
Colliou, V
Cirelli, AF
Sinay, P
机构
[1] Univ Buenos Aires, Fac Ciencias Exactas & Nat, Dept Quim Organ, RA-1428 Buenos Aires, DF, Argentina
[2] Ecole Normale Super, Dept Chim, CNRS, F-75231 Paris 05, France
关键词
D O I
10.1080/07328300008544061
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
The C-disaccharide analogue of the sequence beta-D-Galf-(1-->3)-beta-D-Glcp, an internal disaccharide of the capsular polysaccharide of Klebsiella K14 was synthesized by radical macrocyclization of temporarily tethered monosaccharides. The alpha-difluoro-C-analogue was obtained in three steps from D-galactono-1,4-lactone.
引用
收藏
页码:1 / 12
页数:12
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