Mild Rh(III)-Catalyzed Direct C-H Bond Arylation of (Hetero)Arenes with Arylsilanes in Aqueous Media

被引：112
|
作者：
Lu, Ming-Zhu [1 ,2 ]
Lu, Ping [1 ,2 ]
Xu, Yun-He [1 ,2 ]
Loh, Teck-Peng [1 ,2 ,3 ]
机构：
[1] Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Peoples R China
[2] Univ Sci & Technol China, Dept Chem, Hefei 230026, Peoples R China
[3] Nanyang Technol Univ, Sch Phys & Math Sci, Div Chem & Biol Chem, Singapore 637371, Singapore
来源：
ORGANIC LETTERS | 2014年 / 16卷 / 10期
基金：
中国国家自然科学基金;
关键词：
CROSS-COUPLING REACTIONS; OXIDATIVE OLEFINATION; INDOLE ALKALOIDS; RHODIUM; FUNCTIONALIZATION; ACTIVATION; ARENES; DERIVATIVES; VERSATILE; ACCESS;
D O I：
10.1021/ol500754h
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An efficient rhodium(III)-catalyzed C-H bond activation and further direct arylation of (hetero)arenes with organosilanes in aqueous media was developed. This reaction shows good substrate scope and excellent functional group compatibility and gives the products in good yields with excellent regioselectivity.
引用
收藏
页码：2614 / 2617
页数：4
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