Synthesis, structure and characterisation of a Mn(IV) complex with a potentially tridentate phosphinothiol ligand

被引:7
|
作者
Pérez-Lourido, P
Romero, J
Rodríguez, L
García-Vázquez, JA
Castro, J
Sousa, A [1 ]
Dilworth, JR
Nascimento, OR
机构
[1] Univ Santiago de Compostela, Fac Quim, Dept Quim Inorgan, Santiago De Compostela 15706, Spain
[2] Univ Vigo, Dept Quim Inorgan, Pontevedra 36200, Spain
[3] Univ Oxford, Inorgan Chem Lab, Oxford OX1 3QR, England
[4] Univ Sao Paulo, Intituto Fis Sao Carlos, Sao Paulo, Brazil
关键词
crystal structure; Mn(IV) complexes; phosphinothiolate complexes; cyclic voltammetry;
D O I
10.1016/S1387-7003(02)00392-1
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The manganese(IV) complex, [Mn{PhP(C6H4S-2)(2)}(2)], was synthesised by direct reaction between manganese(II) acetate and the proligand bis(2-mercaptophenyl)phenylphosphine in methanol and characterised by elemental analysis, mass spectrometry, cyclic voltammetry and X-ray crystallography. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:337 / 339
页数:3
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