On the influence of ionicity over catalysis in ionic liquids

被引：0
|
作者：
Gutel, Thibaut [1 ]
Campbell, Paul [1 ]
Santini, Catherine C. [1 ]
Lefebvre, Frederic [1 ]
Lucas, Christine [1 ]
Chauvin, Yves [1 ]
机构：
[1] Univ Lyon, Inst Chim Lyon, Equipe Chim Organomet Surface, CNRS,ESCPE Lyon,C2P2,UMR 5265, F-69626 Villeurbanne, France
来源：
CHIMICA OGGI-CHEMISTRY TODAY | 2009年 / 27卷 / 01期
关键词：
ISOMERIZATION;
D O I：
暂无
中图分类号：
Q81 [生物工程学（生物技术）]; Q93 [微生物学];
学科分类号：
071005 ; 0836 ; 090102 ; 100705 ;
摘要：
The cation exchange reaction between the sodium cation [Na](+) of (m-sulfophenyl)-diphenylphosphine sodium salt, [Ph2P(C6H4SO3](-)[Na](+), (L-1), and the imidazolium cations of ionic liquids (ILs), evidenced by solid state Na-23 NMR, governs the catalytic activity in the isomerization reaction of 2-methyl-3-butenenitrile (2M3BN) to 3-pentenenitrile (3PN) catalyzed by a mixture of bis(1,5-cyclooctadiene)nickel(0), Ni(COD)(2) and (L-1), in ILs.
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页码：48 / 50
页数：3
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