Nucleation tendency and crystallizing phase in silicate glasses: A structural aspect

被引:16
|
作者
Takahashi, Yoshihiro [1 ]
Masai, Hirokazu [1 ]
Fujiwara, Takumi [1 ]
机构
[1] Tohoku Univ, Dept Appl Phys, Aoba Ku, Sendai, Miyagi 9808579, Japan
关键词
barium compounds; crystallisation; glass; glass structure; nucleation; silicon compounds; RICH BARIUM SILICATES; GROWTH-KINETICS; RANGE ORDER; REFINEMENT; CHEMISTRY; FRESNOITE; DIOPSIDE; LI2SI2O5; FORMERS; LIQUIDS;
D O I
10.1063/1.3206931
中图分类号
O59 [应用物理学];
学科分类号
摘要
We consider the relationship of nucleation tendency with crystallizing-phase structures in silicate glasses using glassy sanbornite (1BaO-2SiO(2)) that shows homogeneous nucleation resulting crystallization of Ba(5)Si(8)O(21) and beta-BaSi(2)O(5) phases with a layered structure of a network modifier and a network former. This trend is also confirmed in other silicate glasses with homogeneous nucleation tendency, which has been assessed by Zanotto and other researchers. It is suggested that the structural dimension of the crystallizing phase governs the nucleation tendency in silicate glasses.
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页数:3
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