2-Hydroxylation of 1,3-Diketones with Atmospheric Oxygen

被引：17
|
作者：
Li, Zheng [1 ]
Li, Tianpeng [1 ]
Li, Jiasheng [1 ]
He, Lili [1 ]
Jia, Xianggui [1 ]
Yang, Jingya [1 ]
机构：
[1] Northwest Normal Univ, Coll Chem & Chem Engn, Lanzhou 730070, Gansu, Peoples R China
来源：
SYNLETT | 2015年 / 26卷 / 20期
基金：
中国国家自然科学基金;
关键词：
diketones; hydroxylations; oxidations; green chemistry; BETA-DICARBONYL COMPOUNDS; CATALYZED ALPHA-HYDROXYLATION; 1,3-DICARBONYL COMPOUNDS; STEREOCONTROL; OXIDATION;
D O I：
10.1055/s-0035-1560647
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An efficient method for the 2-hydroxylation of 1,3-diketones by using atmospheric oxygen as an oxidant under transition-metal-free condition is described. The protocol has the advantages of using an inexpensive and stable oxidant, producing high yields, and requiring ecofriendly conditions.
引用
收藏
页码：2863 / 2865
页数：3
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