Syntheses and crystal structures of two Schiff-base copper(II) complexes with urease inhibition

被引：20
|
作者：
Wang, Chen-Yi [1 ]
Ye, Jin-Yun [1 ]
Lv, Chun-Yan [1 ]
Lan, Wei-Zhen [1 ]
Zhou, Jun-Bo [1 ]
机构：
[1] Huzhou Univ, Dept Chem, Huzhou 313000, Peoples R China
来源：
JOURNAL OF COORDINATION CHEMISTRY | 2009年 / 62卷 / 13期
关键词：
Schiff base; copper(ii) complex; synthesis; crystal structure; urease inhibitory property; KLEBSIELLA-AEROGENES UREASE; X-RAY-STRUCTURE; S-BENZYLDITHIOCARBAZATE; METAL-COMPLEXES; BIOACTIVITY; LIGANDS; CU;
D O I：
10.1080/00958970902801493
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two new copper(II) complexes, [CuL1(N3)] (1) and [CuL2(NCS)] (2) (HL1 = 4-chloro-2-[(2-piperidin-1-ylethylimino)methyl]phenol, HL2 = 4-chloro-2-[(2-morpholin-4-ylethylimino)methyl]phenol), were prepared and structurally characterized by elemental analyses, infrared spectroscopy, and single-crystal X-ray diffraction. Complex 1 is an azide coordinated mononuclear complex, while complex 2 is a terminal thiocyanate coordinated mononuclear complex. The coppers in both complexes are four-coordinate, square-planar. Both complexes show potent urease inhibitory properties.
引用
收藏
页码：2164 / 2171
页数：8
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