Vibrational analysis and normal coordinate analysis of trimethylphosphane

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作者
Pikl, R
Fickert, C
Kiefer, W
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O65 [分析化学];
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070302 ; 081704 ;
摘要
Raman spectra of trimethylphosphine {P(CH3)(3)} as Liquid have been recorded with parallel and perpendicular polarization. Vibrational assignments are given by means of a normal coordinate analysis. The skeletal modes of the phosphorus-carbon-core and their interactions with the methyl groups, its force field and potential energy distribution are discussed.
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页码:351 / 353
页数:3
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