Ordering and interaction of molecules encapsulated in carbon nanotubes

被引：6
|
作者：
Khlobystov, AN
Porfyrakis, K
Britz, DA
Kanai, M
Scipioni, R
Lyapin, SG
Wiltshire, JG
Ardavan, A
Nguyen-Manh, D
Nicholas, RJ
Pettifor, DG
Dennis, TJS
Briggs, GAD
机构：
[1] Univ Oxford, Dept Mat, Oxford OX1 3PH, England
[2] Univ Oxford, Dept Phys, Oxford OX1 3PU, England
[3] Queen Mary Univ London, Ctr Mat Res, London E1 4NS, England
来源：
MATERIALS SCIENCE AND TECHNOLOGY | 2004年 / 20卷 / 08期
关键词：
carbon nanotubes; self-assembly; fullerenes; van der Waals interactions; hydrogen bonding;
D O I：
10.1179/174328413X13789824293425
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
A clear understanding of the interactions between the building blocks of self-assembled molecular materials is essential for rational design of functional nanostructures. Intermolecular interactions have been investigated for three different classes of fullerenes in single-walled carbon nanotubes (SWNTs); van der Waals molecule -molecule and molecule-SWNT interactions control the geometry of the molecular arrays inside nanotubes; electrostatic intermolecular forces influence the alignment of polar endohedral fullerenes M@C-82; and hydrogen bonding between functionalised fullerenes has a significant effect on the selectivity of insertion of functionalised fullerenes into SWNTs.
引用
收藏
页码：969 / 974
页数：6
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