Synthesis and characterization of optically active cyclic 6,6'-dinitro-1,1'-binaphthyl-2,2'-diethers

被引：32
|
作者：
vanEs, JJGS [1 ]
Biemans, HAM [1 ]
Meijer, EW [1 ]
机构：
[1] EINDHOVEN UNIV TECHNOL,DEPT ORGAN CHEM,NL-5600 MB EINDHOVEN,NETHERLANDS
来源：
TETRAHEDRON-ASYMMETRY | 1997年 / 8卷 / 11期
关键词：
D O I：
10.1016/S0957-4166(97)00185-7
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A series of racemic and enantiomerically pure 6,6'-dinitro-1,1'-binaphthyl-2,2'-diethers 1 have been synthesized by the nitration of the corresponding cyclic ethers and both the reactivity of nitration and the (chir)optical properties proved to be very sensitive for the chain length of the ether bridge. (C) 1997 Elsevier Science Ltd.
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页码：1825 / 1831
页数：7
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