Thiolato-bridged hexanuclear CuICuII mixed-valence complex

被引：6
|
作者：
Kotera, T [1 ]
Mikuriya, M [1 ]
机构：
[1] Kwansei Gakuin Univ, Sch Sci & Technol, Dept Chem, Sanda 6691337, Japan
来源：
CHEMISTRY LETTERS | 2002年 / 07期
关键词：
D O I：
10.1246/cl.2002.654
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Thiolato-bridged hexanuclear mixed-valence complex, [(Cu3Cu3II)-Cu-I(apampt)(3)Cl-6] (Hapampt = 1-[(3-aminopropyl)amino]-2-methylpropane-2-thiol), has been synthesized and characterized by X-ray crystallography. Spectroscopic data as well as structural features support a localized mixed-valence state. Magnetic susceptibility data show that a strong anti ferromagnetic interaction is operating between the Cull ions.
引用
收藏
页码：654 / 655
页数：2
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