Ternary NiS/ZnxCd1-xS/Reduced Graphene Oxide Nanocomposites for Enhanced Solar Photocatalytic H2-Production Activity

被引:216
|
作者
Zhang, Jun [1 ,2 ]
Qi, Lifang [1 ]
Ran, Jingrun [2 ]
Yu, Jiaguo [1 ]
Qiao, Shi Zhang [2 ]
机构
[1] Wuhan Univ Technol, State Key Lab Adv Technol Mat Synth & Proc, Wuhan 430070, Peoples R China
[2] Univ Adelaide, Sch Chem Engn, Adelaide, SA 5005, Australia
基金
澳大利亚研究理事会;
关键词
P-N-JUNCTION; HYDROGEN EVOLUTION; H-2; EVOLUTION; ARTIFICIAL PHOTOSYNTHESIS; AQUEOUS-SOLUTIONS; WATER; CDS; OXYGEN; TIO2; SEMICONDUCTOR;
D O I
10.1002/aenm.201301925
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A ternary ZnxCd1-xS-based material in the co-presence of NiS and reduced graphene oxide (RGO) is designed and synthesized. It shows a high solar photocatalytic H2-production activity and the apparent quantum efficiency of 31.1% at 420 nm. This represents one of the most active metal sulfide photocatalysts in the absence of noble-metal cocatalysts and the significantly improved performance can be attributed to the positive synergetic effect of NiS and RGO over ZnxCd1-xS. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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页数:6
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