The Kunene Complex (KC) of SW Angola, covering an area of 15,000km(2), is one of the largest anorthosite bodies in the world. Although considered by several authors as a layered complex, field evidences demonstrate that it is a massive anorthosite. In the study area, a Northern and a Southern KC were distinguished on the basis of a clear difference in anorthite contents. The boundary between them corresponds to a belt of coeval granitoids. Analyses of two multigrain zircon populations and several single-grains (evaporation and vapour dissolution methods) from a late-stage mangerite vein, inferred to be cogenetic with the KC, yielded a concordant age of 13714 +/- 2.5 Ma, implying a Meso-proterozoic age for the KC. Because the anorthosites are unmetamorphosed, cooling after emplacement was also constrained by Sm-Nd mineral isochrons of 1470 +/- 25 Ma, for a troctolite near Quihita, and 1319 +/- 28 Ma, for a hyperporphyritic "megacrystic" anorthosite dyke, considered to represent a quenched plagioclase crystal-mush, sampled near Lufinda. The discrepancy between the two data can be interpreted in two ways: (1) the Sm-Nd isochrons are geologically meaningful, and thus the KC is constituted by various plutons with different Mesoproterozoic ages; (2) most likely, the Sm-Nd systematic was cryptically perturbed at mineral-scale. and thus only the U-Pb age of the mangerite vein yields to a reliable intrusion age of the KC. The initial Nd-143/Nd-144 of the Quihita sample (0.510734 +/- 28), as well as the high anorthite content of Northern KC, suggests that parent magma of KC derived from a mantle-source, and thus that the emplacement of KC anorthosites reflect an episode of continental accretion rather than a within-continent differentiation. The initial Nd-143/Nd-144 of the Lufinda dyke (0.510766 +/- 24) implies instead a minor addition of crustal material into the parental magma. Collectively, the emplacement of the Kunene Complex requires an extensional setting and a significant thermal anomaly at the margin of the Congo Craton during the early Kibaran cycle. (C) 2004 Elsevier B.V. All rights reserved.