Geochemical assessment of the newly discovered oil-type Shale in the Shuangcheng area of the northern Songliao Basin, China

For the past fifty years, the northern Songliao Basin in China was thought to contain Lower Cretaceous coal-measure and gas-generating shale. Oil-type shales did not receive much attention until oil exploration activities made a breakthrough in the Southern Shuangcheng (SSC) depression. In this study, the geochemical characteristics of the newly discovered K(1)yc(4) (fourth member of the Lower Cretaceous YingCheng Formation) oil-type shale in the SSC depression were analyzed, including the organic matter abundance, organic matter type, thermal maturity, hydrocarbon potential, and sedimentary environment. A total of 393 core samples were collected, and Rock-Eval pyrolysis, gas chromatography-mass spectrometry (GC-MS), organic petrography, carbon isotope analysis, and constant and trace element analyses were conducted. The K(1)yc(4) shale was determined to have a good to excellent hydrocarbon potential with high TOC values (mostly 2.0-4.0%). The organic matter was mainly from lower hydrobiont, algae, bacteria, and lesser amounts of terrestrial plants. The organic matter is mainly type Ito type II based on the hydrogen index (HI) (average HI = 193.36 mg HC/g TOC), the carbon isotopes of the kerogen (mostly -26 to -30 parts per thousand), and the organic petrography (average sapropelinite + liptinite of 55.0 vol%). The maturity parameters, i.e., T-max (mean 452 degrees C) and vitrinite reflectance (0.8-1.1%), suggest that the shale is in the mature thermal evolution stage. The shale's maximum hydrocarbon-generating intensity is up to 713.29 x 10(4)/km(2), and its hydrocarbon-expelling intensity is stable at 116.63 x 10(4)/km(2). The constant and trace element analyses (Sr, Ba, V, Ni, Cr, Ti) revealed that the organic matter deposition and preservation occurred in a fresh-brackish and dysoxic-anoxic water environment. Volcanic eruptions probably played a vital role in the enrichment of the organic matter in the oil-type shale. In addition, the results of this study provide evidence that the Lower Cretaceous strata in the northern Songliao Basin meet the geological conditions of oil-prone shale, which expands the petroleum exploration horizon in this region.