Study of Silver(I) Complex Formation with Some Thiourea Derivatives in Aqueous Solution

被引：5

作者：

Samadov, A. S. ^{[1
]}

Mironov, I. V. ^{[2
]}

Gorichev, I. G. ^{[1
]}

Kovalchukova, O. V. ^{[3
]}

Stepnova, A. F. ^{[1
]}

机构：

[1] Moscow State Pedag Univ, Moscow 129164, Russia

[2] Russian Acad Sci, Siberian Branch, AV Nikolaev Inst Inorgan Chem, Novosibirsk 630090, Russia

[3] Russian Univ Friendship Peoples, Moscow 115419, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2020年 / 90卷 / 11期

关键词：

complexation; silver(I) ions; thiourea derivatives; stability constant; potentiometry; IONS;

D O I：

10.1134/S1070363220110146

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The equilibrium processes of the formation of mononuclear and some binuclear silver(I) complexes with thiourea, N-acetylthiourea, thiosemicarbazide, N-phenylthiourea, and N,NMODIFIER LETTER PRIME-diphenylthiourea at 25 degrees C and I = 0.11 M. (0.01 M HNO3 + 0.1 M NaNO3) in aqueous solution were studied by potentiometry method with a silver electrode. The stability constants of the complexes were determined. The stability of mononuclear complexes is almost identical for all the ligands, except for complexes with acetylthiourea, for which it is lower.

引用

页码：2111 / 2114

页数：4

共 50 条

[1] Study of Silver(I) Complex Formation with Some Thiourea Derivatives in Aqueous Solution
A. S. Samadov
I. V. Mironov
I. G. Gorichev
O. V. Kovalchukova
A. F. Stepnova
[J]. Russian Journal of General Chemistry, 2020, 90 : 2111 - 2114
[2] Stability of mononuclear and binuclear silver(I) complexes with thiourea in aqueous solution
Mironov, IV
Tsvelodub, LD
[J]. ZHURNAL NEORGANICHESKOI KHIMII, 1996, 41 (02): : 240 - 244
[3] On the Reactivity of Thiourea Derivatives with Silver(I) Oxide
Pilz, Sarah K.
Mohr, Fabian
[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2020, 2020 (23) : 2285 - 2294
[4] A POTENTIOMETRIC STUDY ON COMPLEX-FORMATION OF SILVER(I) ION WITH GLYCINE AND BETA-ALANINE IN AQUEOUS-SOLUTION
OHTAKI, H
ZAMA, M
KOYAMA, H
ISHIGURO, S
[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1980, 53 (10) : 2865 - 2867
[5] IDENTIFICATION OF A SILVER(I)CARBONYL COMPLEX IN AQUEOUS-SOLUTION
BACKEN, W
VESTIN, R
[J]. ACTA CHEMICA SCANDINAVICA SERIES A-PHYSICAL AND INORGANIC CHEMISTRY, 1980, 34 (01): : 73 - 74
[6] FORMATION OF SOME COMPLEX COMBINATIONS WITH PIPERAZINE IN AQUEOUS SOLUTION
POPA, G
MAGEARU, V
[J]. REVUE ROUMAINE DE CHIMIE, 1969, 14 (11) : 1387 - &
[7] COMPLEX-FORMATION OF SILVER WITH THIOUREA AND ITS DERIVATIVES IN WATER-DIMETHYLFORMAMIDE SOLUTIONS
BAIBAROVA, EY
MOVCHAN, VV
DZYUBA, OG
TULYUPA, FM
[J]. ZHURNAL NEORGANICHESKOI KHIMII, 1978, 23 (06): : 1546 - 1549
[8] COMPLEX-FORMATION OF COPPER(I) WITH THIOUREA AND ITS DERIVATIVES IN PRESENCE OF DIMETHYLFORMAMIDE
MOVCHAN, VV
BAIBAROVA, EY
MARTYNYUK, TA
TULYUPA, FM
[J]. ZHURNAL NEORGANICHESKOI KHIMII, 1978, 23 (07): : 1847 - 1851
[9] Mixed complex formation of lead(II) and mercury(II) ethylenediaminetetraacetates with thiourea in an aqueous solution
D. F. Pyreu
E. V. Kozlovskii
M. S. Gruzdev
R. S. Kumeev
[J]. Russian Journal of Coordination Chemistry, 2011, 37 : 730 - 737
[10] Mixed Complex Formation of Lead(II) and Mercury(II) Ethylenediaminetetraacetates with Thiourea in an Aqueous Solution
Pyreu, D. F.
Kozlovskii, E. V.
Gruzdev, M. S.
Kumeev, R. S.
[J]. RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2011, 37 (10) : 730 - 737

← 1 2 3 4 5 →