Synthesis and crystal structure of N-heterocyclic carbene complex of silver

被引：46

作者：

Chen, WZ ^{[1
]}

Wu, B ^{[1
]}

Matsumoto, K ^{[1
]}

机构：

[1] Waseda Univ, JST, Adv Res Inst Sci & Engn, Dept Chem,Shinjuku Ku, Tokyo 1698555, Japan

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2002年 / 654卷 / 1-2期

关键词：

carbene; imidazolium salts; silver complex; X-ray structures;

D O I：

10.1016/S0022-328X(02)01411-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New imidazolium salt, [m-C6H4(CH(2)ImMe)(2)]Cl-2 (1) was prepared by quaterization of N-methylimidazole with m-xylylene dichloride. A novel monocarbene silver dinulear complex, [m-C6H4(CH(2)ImMeAgCl)(2)] (3) was obtained by reacting 1 and Ag2O in CH2Cl2. The structure of 3 was determined by X-ray crystallography. The geometry around the Ag atoms in 3 is linear, and each Ag atom is bi-coordinated by a carbon and chloride ion. 200(C)2 Published by Elsevier Science B.V.

引用

页码：233 / 236

页数：4

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