Extraction of cesium into nitrobenzene using hydrogen dicarbollylcobaltate in the presence of dibenzo-24-crown-8

被引:3
|
作者
Vanura, P [1 ]
Makrlík, E [1 ]
Valentová, Z [1 ]
机构
[1] Univ W Bohemia, Inst Interdisciplinary Studies, Plzen 30614, Czech Republic
关键词
D O I
10.1007/BF03191387
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Extraction of microamounts of cesium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H+B-) in the presence of dibenzo-24-crown-8 (DB24C8,L) has been investigated. The equilibrium data have been explained assuming that the complexes HL+ and CsL+ are extracted into the organic phase. The values of extraction and stability constants of the species in nitrobenzene saturated with water have been determined.
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页码:527 / 529
页数:3
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