Thermochromic and Magnetic Properties of a Copper(II) Coordination Compound

被引：1

作者：

Cai Lin-Rong ^{[1
,2
]}

Cai Li-Zhen ^{[2
]}

Chen Zi-Wei ^{[2
]}

Sun Cai ^{[2
]}

Xing Xiu-Shuang ^{[3
]}

Wang Ming-Sheng ^{[2
]}

Guo Guo-Cong ^{[2
]}

机构：

[1] Fujian Normal Univ, Coll Mat Sci & Engn, Fuzhou 350007, Peoples R China

[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China

[3] Fuzhou Univ, Coll Chem, Fuzhou 350108, Peoples R China

来源：

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2017年 / 36卷 / 01期

关键词：

copper complex; magnetism; solid state; thermochromism; STRUCTURAL-CHARACTERIZATION; CRYSTAL-STRUCTURES; SINGLE-CRYSTAL; SOLID-STATE; COMPLEXES; TEMPERATURE; PHOTOCHROMISM; LIGANDS; POLYMER; 4,4'-BIPYRIDINE;

D O I：

10.14102/j.cnki.0254-5861.2011-1169

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Copper complexes that can experience reversible heat-induced dehydration and rehydration in the solid state were rarely reported although thermochromic copper complexes have been widely reported, and their heat-induced magnetic properties have not been studied. We firstly observed the reversible thermochromic phenomena of the known copper(II) complex [Cu(bpy)(OOCCH3)(2)](n)center dot xnH(2)O (x = 2.5 or 3; bpy = 4,4'-bipyridine) in the solid state, which is associated with the dehydration and rehydration processes, and found that heat-induced coloration clearly enhanced the magnetic susceptibility.

引用

页码：40 / 46

页数：7

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