Mesoporous sBa-15 silica catalyst functionalized with phenylsulfonic acid groups (SbA-15-ph-So3h) as efficient nanocatalyst for chemoselective thioacetalization of carbonyl compounds

被引:5
|
作者
Sedrpoushan, Alireza [1 ]
Ghazizadeh, Habibollah [1 ]
机构
[1] IROST, Inst Ind Chem, Tehran, Iran
关键词
Mesoporous material; solid acid catalyst; thioacetals; chemoselective; PHENYL SULFONIC-ACID; HETEROGENEOUS CATALYST; RECYCLABLE CATALYST; FE3O4; NANOPARTICLES; COUPLING REACTION; MILD CONDITIONS; ALDEHYDES; PROTECTION; ACETALIZATION; DEPROTECTION;
D O I
10.1080/17415993.2016.1257929
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In this research a Nano acidic catalyst was prepared and its efficiency on thioacetalization of carbonyl compounds was examined. For this aim we used modified SBA-15 as support, which have been modified by phenolic and sulfonic acid. SBA-15 is a member of mesoporouses. Mesostructures-based properties such as large specific surface, low specific weight, chemical and thermal resistance have been used in different fields such as catalyst, drug delivery, chromatography, microelectronic, separation and purification. Based on our knowledge mesoporoses are ideal catalysts and usually have been used as solid catalyst, which have been modified by organic groups and metal oxides. These types of application are based on the large dispersability of the modifier groups at mesoporouses. [GRAPHICS]
引用
收藏
页码:112 / 118
页数:7
相关论文
共 50 条
  • [1] Phenylsulfonic acid functionalized mesoporous SBA-15 silica: A heterogeneous catalyst for removal of free fatty acids in vegetable oil
    Xie, Wenlei
    Qi, Cong
    Wang, Hongyan
    Liu, Yawei
    [J]. FUEL PROCESSING TECHNOLOGY, 2014, 119 : 98 - 104
  • [2] Direct synthesis of SBA-15 mesoporous silica functionalized with sulfonic acid groups
    Yuan, XD
    Shen, J
    Li, GH
    Zhou, JL
    Kim, JM
    Park, SE
    [J]. CHINESE JOURNAL OF CATALYSIS, 2003, 24 (02) : 83 - 86
  • [3] Mesoporous SBA-15 Silica Phenylsulfonic Acid (SBA-15-Ph-SO3H) as Efficient Nanocatalyst for One-pot Three-component Synthesis of 3-Methyl-4-aryl-2,4,5,7-tetrahydropyrazolo[3,4-b]pyridine-6-ones
    Veisi, Hojat
    Hekmati, Malak
    Hemmati, Saba
    [J]. JOURNAL OF HETEROCYCLIC CHEMISTRY, 2017, 54 (02) : 1630 - 1635
  • [4] Preparation and catalytic activity or SBA-15 mesoporous silica functionalized with sulfonic acid groups
    Yuan, XD
    Shen, J
    Li, GH
    Kim, JM
    Park, SE
    [J]. CHINESE JOURNAL OF CATALYSIS, 2002, 23 (05) : 435 - 438
  • [5] Synthesis of Cu nanoparticles in mesoporous silica SBA-15 functionalized with carboxylic acid groups
    Chen, Ching-Shiun
    Chen, Chen-Chih
    Chen, Ching-Ting
    Kao, Hsien-Ming
    [J]. CHEMICAL COMMUNICATIONS, 2011, 47 (08) : 2288 - 2290
  • [6] B–SBA-15–SO3H: a versatile mesoporous catalyst
    Beyhan Erdem
    Çağla Azko
    [J]. Journal of Porous Materials, 2017, 24 : 1237 - 1246
  • [7] Propylsulfonic Acid Functionalized SBA-15 Mesoporous Silica as Efficient Catalysts for the Acetalization of Glycerol
    Li, Ruiyun
    Song, Heyuan
    Chen, Jing
    [J]. CATALYSTS, 2018, 8 (08)
  • [8] A mesoporous SBA-15 silica catalyst functionalized with phenylsulfonic acid groups (SBA-15-Ph-SO3H) as a novel hydrophobic nanoreactor solid acid catalyst for a one-pot three-component synthesis of 2H-indazolo[2,1-b]phthalazine-triones and triazolo[1,2-a]indazole-triones
    Veisi, Hojat
    Sedrpoushan, Alireza
    Faraji, Ali Reza
    Heydari, Masoud
    Hemmati, Saba
    Fatahi, Behnaz
    [J]. RSC ADVANCES, 2015, 5 (84) : 68523 - 68530
  • [9] Mesoporous silica SBA-15 functionalized with phosphonate and amino groups for uranium uptake
    XiaoLiang Wang
    LiYong Yuan
    YanFei Wang
    ZiJie Li
    JianHui Lan
    YaLan Liu
    YiXiao Feng
    YuLiang Zhao
    ZhiFang Chai
    WeiQun Shi
    [J]. Science China Chemistry, 2012, 55 : 1705 - 1711
  • [10] Mesoporous silica SBA-15 functionalized with phosphonate and amino groups for uranium uptake
    Wang XiaoLiang
    Yuan LiYong
    Wang YanFei
    Li ZiJie
    Lan JianHui
    Liu YaLan
    Feng YiXiao
    Zhao YuLiang
    Chai ZhiFang
    Shi WeiQun
    [J]. SCIENCE CHINA-CHEMISTRY, 2012, 55 (09) : 1705 - 1711