A binaphtolate titanium complex featuring a linear tetradentate [OSSO]-bis(phenolato) ligand: Synthesis and partial hydrolysis to a homochiral dinuclear complex

被引：10
|
作者：
Meppelder, Geert-Jan M. [1 ]
Spaniol, Thomas P. [1 ]
Okuda, Jun [1 ]
机构：
[1] Rhein Westfal TH Aachen, Inst Inorgan Chem, D-52074 Aachen, Germany
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2006年 / 691卷 / 14期
关键词：
titanium; chiral complexes; C-2-symmetry; phenolato ligands;
D O I：
10.1016/j.jorganchem.2006.02.006
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reaction of [{(R)-C20H12O2}Ti((OPr)-Pr-i)(2)] with 1,4-dithiaalkanediyl-2,2'-bis(6- tert-butyl-4-methyl-phenol) affords the chiral-at-metal complex [{(R)-C20H12O2} Ti{(C6H2O-'Bu-6-Me-4)(2)S(CH2)(2)S}] (1) in low diastereomeric excess. Complex I can be partially hydrolyzed to give a dinuclear species [mu-{(R)-C20H12O2}-mu-O-{(Lambda)-Ti[(C6H2O-Bu-t-6-Me-4)(2)S(CH2)(2)S]}(2)] (2), in which the two titanium centers are homochiral. The molecular structure of 1 and 2 was confirmed by single crystal X-ray analysis, which shows C-2-symmetry in both complexes. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码：3206 / 3211
页数：6
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