Facile Synthesis of Co3O4 Nanosheets Electrode with Ultrahigh Specific Capacitance for Electrochemical Supercapacitors

被引:72
|
作者
Pan, Xuexue [1 ]
Chen, Xinman [1 ]
Li, Yan [1 ]
Yu, Zenan [2 ]
机构
[1] S China Normal Univ, Inst Optoelect Mat & Technol, Guangdong Engn Technol Res Ctr Optoelect Funct, Guangdong Prov Key Lab Nanophoton Funct Mat & Dev, Guangzhou 510631, Guangdong, Peoples R China
[2] Univ Cent Florida, Dept Mat Sci & Engn, NanoSci Technol Ctr, Orlando, FL 32817 USA
基金
高等学校博士学科点专项科研基金;
关键词
Supercapacitors; Electrodeposition; Co3O4; nanosheets; Specific capacitances; CORE/SHELL NANOWIRE ARRAYS; NI FOAM; ULTRATHIN; NANOPARTICLES; CONSTRUCTION; INTEGRATION; FILM;
D O I
10.1016/j.electacta.2015.10.035
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
The Co3O4 nanosheets electrode have been fabricated on Ni foam by a facile synthesis process including the electrodeposition of Co(OH)(2) precursor followed by subsequent thermal transformation of precursor to Co3O4. The resulting Co3O4 nanosheets electrode exhibits an ultrahigh specific capacitance of 6469 F g(-1) at a current density of 5 mA cm(-2), exceeding their theoretical value. Moreover, at density of 15 mA cm(-2), the specific capacitance maintains 4127 F g(-1), with 81.6% retention after 2000 chargedischarge cycles. The work confirms the promising application of Co3O4 nanosheets as an efficient electrode for supercapacitors, and also offers a facile strategy to design and synthesis Co3O4 electrode with enhanced specific capacitance. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1101 / 1106
页数:6
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