Synthesis of hierarchical α-Fe2O3 nanotubes for high-performance lithium-ion batteries

被引:32
|
作者
Gu, Cuiping [1 ]
Song, Xinjie [2 ]
Zhang, Simin [1 ]
Ryu, Si Ok [3 ]
Huang, Jiarui [1 ]
机构
[1] Anhui Normal Univ, Ctr Nano Sci & Technol, Coll Chem & Mat Sci, Wuhu 241000, Anhui, Peoples R China
[2] Yeungnam Univ, Dept Food Sci & Technol, Gyongsan 712749, Gyeongbuk, South Korea
[3] Yeungnam Univ, Sch Chem Engn, Gyongsan 712749, Gyeoungbuk, South Korea
基金
中国国家自然科学基金;
关键词
Fe2O3; Nanotubes; Sacrificial template method; Lithium-ion batteries; OXIDE HOLLOW NANOSTRUCTURES; ANODE MATERIAL; ELECTROCHEMICAL PERFORMANCE; COMPOSITE; CARBON; FABRICATION; NANOPARTICLES; NANOMATERIALS; NANOFIBERS; MECHANISM;
D O I
10.1016/j.jallcom.2017.04.216
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Hierarchical alpha-Fe2O3 nanotubes are facially synthesized via a sacrificial template strategy without chemical etching, and are then employed as the anode material for lithium-ion batteries (LIBs). FeC2O4 center dot 2H(2)O nanorods are used as the sacrificial template to prepare nanotubes consisting of numerous nanosheets. The resultant hierarchical hollow structures possess an inter-diameter range of 400-600 nm and exhibit a large specific surface area. The as-prepared hierarchical nanotubes demonstrate remarkable improvement in cycling stability (500 cycles) and a reversible Li+ storage capacity as high as 764.2 mAh g (-1) at a current density of 0.5 A g (-1). This excellent electrochemical performance suggests that the hierarchical alpha-Fe2O3 nanotubes prepared herein are promising candidate anode materials for LIBs. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码:6 / 12
页数:7
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