Synthesis of dimethyl carbonate from carbon dioxide: catalysis and mechanism

被引：137

作者：

Sakakura, T ^{[1
]}

Choi, JC ^{[1
]}

Saito, Y ^{[1
]}

Sako, T ^{[1
]}

机构：

[1] Natl Inst Mat & Chem Res, Tsukuba, Ibaraki 3058565, Japan

来源：

POLYHEDRON | 2000年 / 19卷 / 05期

关键词：

carbon dioxide; dimethyl carbonate; homogeneous catalysis; mechanism; supercritical conditions;

D O I：

10.1016/S0277-5387(99)00411-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The turnover number of the catalytic production of dimethyl carbonate from CO2 and methanol is restricted by thermodynamics as well as catalyst decomposition. The catalytic efficiency is remarkably improved using an acetal as the starting material in methanol. The catalytic activity and selectivity also depend strongly on the CO2 pressure. A possible catalytic cycle involving transformation of CO2 to dimethyl carbonate is postulated based on mechanistic studies at a molecular level. (C) 2000 Elsevier Science Ltd All rights reserved.

引用

页码：573 / 576

页数：4

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