Synthesis and characterization of (NH4)4[H4V10O28][NTPH2]2•4H2O (NTPH3 = N(CH2CH2COOH)3)

被引：17
|
作者：
Chinea, E
Dakternieks, D
Duthie, A
Ghilardi, CA
Gill, P
Mederos, A
Midollini, S
Orlandini, A
机构：
[1] CNR, Ist Studio Stereochim & Energet Composti Coor, I-50132 Florence, Italy
[2] Univ La Laguna, Dept Quim Inorgan, Tenerife 38200, Canary Isl, Spain
[3] Deakin Univ, Ctr Chiral & Mol Technol, Geelong, Vic 3217, Australia
来源：
INORGANICA CHIMICA ACTA | 2000年 / 298卷 / 02期
关键词：
crystal structures; electrospray mass spectrometry; polyoxovanadates;
D O I：
10.1016/S0020-1693(99)00440-5
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reaction of (NH4)VO3 with NTPH3 (=N(CH2CH2COOH)(3)) in water, at controlled pH, allowed the synthesis of (NH4)(4)[H4V10O28][NTPH2](2). 4H(2)O salt, which has been characterized by spectroscopic measurements (NMR), electrospray mass spectrometry (ESMS) and X-ray diffraction studies. The structure is strongly stabilized by an extensive network of hydrogen bonding interactions which involve the tetraprotonated decavanadate anion, NTPH2 ligand anions, ammonium cations and solvent water molecules. (C) 2000 Elsevier Science S.A. All rights reserved.
引用
收藏
页码：172 / 177
页数：6
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