Tuning morphologies of thermoset/thermoplastic blends - Part 1: Kinetic modelling of epoxy-amine reactions using amine mixtures

被引：0

作者：

Lahlali, Nadir ^{[1
]}

Dupuy, Jerome

Dumon, Michel

机构：

[1] Univ Lyon, F-69003 Lyon, France

[2] Inst Natl Sci Appl, IMP LMM Lab Mat Macromol, F-69621 Villeurbanne, France

[3] CNRS, UMR5627, F-69621 Villeurbanne, France

来源：

E-POLYMERS | 2006年

关键词：

D O I：

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中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Different epoxy amine networks based on a mixture of diamine hardeners have been studied and their kinetic behaviour was modelled in order to understand the global and particular behaviour of each diamine in such blends. 4,4'-Diaminodiphenylsulfone (DDS) and 4,4'-methylenebis-(3-chloro-2,6-diethylaniline) (MCDEA) were used for this study by varying the DDS molar ratio from 0% to 50%. The determined kinetic model allowed us to calculate the composition for each diamine of the reactive epoxy-amine system in the whole range of epoxy conversions. Then the influence of 10% thermoplastic additive was checked and it was found to be negligible in the kinetic behaviour.

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页数：12

共 29 条

[1] Tuning morphologies of thermoset /thermoplastic blends Part 1: Kinetic modelling of epoxy-amine reactions using amine mixtures
Lahlali, Nadir
Dupuy, Jérôme
Dumon, Michel
E-Polymers, 2006, : 1 - 12
[2] Polymer blends based on an epoxy-amine thermoset and a thermoplastic
Lopez, J.
Rico, M.
Montero, B.
Diez, J.
Ramirez, Carmen
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2009, 95 (02) : 369 - 376
[3] Tuning morphologies of thermoset/thermoplastic blends - Part 2: Phase separation of poly(vinyl methyl ether), PVME, using amine mixtures as thermoset hardeners
Lahlali, Nadir
Dupuy, Jerome
Dumon, Michel
E-POLYMERS, 2006,
[4] Tuning morphologies of thermoset / thermoplastic blends part 2: Phase separation of poly(vinyl methyl ether), PVME, using amine mixtures as thermoset hardeners
Université de Lyon, Lyon, F-69003, France
不详
不详
不详
E-Polymers, 2006, (1-12)
[5] Polymer blends based on an epoxy-amine thermoset and a thermoplasticEffect of thermoplastic on cure reaction and thermal stability of the system
J. López
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J. Díez
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Journal of Thermal Analysis and Calorimetry, 2009, 95 (2) : 369 - 376
[6] Kinetic method by using calorimetry to mechanism of epoxy-amine cure reaction. Part VIII. A comparative study of some epoxy-amine reactions
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Roznyatovsky, V. A.
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2006, 85 (02) : 455 - 461
[7] Kinetic method by using calorimetry to mechanism of epoxy-amine cure reactionPart VIII. A comparative study of some epoxy-amine reactions
R. M. Vinnik
V. A. Roznyatovsky
Journal of Thermal Analysis and Calorimetry, 2006, 85 : 455 - 461
[8] Self-healing thermoset using encapsulated epoxy-amine healing chemistry
Jin, Henghua
Mangun, Chris L.
Stradley, Dylan S.
Moore, Jeffrey S.
Sottos, Nancy R.
White, Scott R.
POLYMER, 2012, 53 (02) : 581 - 587
[9] Kinetic method by using calorimetry to mechanism of epoxy-amine cure reaction - Part II. On catalytic action of the amine excess
Vinnik, RM
Roznyatovsky, VA
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2003, 73 (03) : 819 - 826
[10] Kinetic method by using calorimetry to mechanism of epoxy-amine cure reaction
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Journal of Thermal Analysis and Calorimetry, 2003, 73 : 819 - 826

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