What I Have Learned from Jack Dunitz

被引：4

作者：

Seebach, Dieter ^{[1
]}

机构：

[1] Swiss Fed Inst Technol, Lab Organ Chem, Vladimir Prelog Weg 3, CH-8093 Zurich, Switzerland

来源：

ISRAEL JOURNAL OF CHEMISTRY | 2017年 / 57卷 / 1-2期

关键词：

crystallography; enolates; lithium; peptides; stereochemistry; CRYSTAL-STRUCTURE; MOLECULAR-STRUCTURE; ORGANIC-SYNTHESIS; BETA-PEPTIDES; REACTION-PATH; LITHIUM; ORGANOCATALYSIS; DERIVATIVES; COMPLEXES; DIFFRACTION;

D O I：

10.1002/ijch.201600010

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The lessons taught me by Jack Dunitz about the use of X-ray crystal structure analysis, far beyond just for determining the structure of an isolated product, are described. The direct and indirect influence Jack had on the way various topics of my synthetic group developed at ETH is demonstrated with selected examples from our various re-search areas: Li-enolates, the gem-diaryl effect and TADDOLs, self-regeneration of stereocenters, poly(hydroxybutanoates) (PHB), beta-peptides, and mechanistic investigations of organocatalytic reactions. Furthermore, the role Jack plays in the Laboratorium of Organic Chemistry at ETH Zurich is described and appreciated.

引用

页码：55 / 65

页数：11

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