Structural and optical properties of polycrystalline MgxZn1-xO and ZnO: Mn films prepared by chemical spray pyrolysis

被引:2
|
作者
Terasako, Tomoaki [1 ]
Yagi, Masakazu [1 ]
Kariya, Tetsuya [1 ]
Shirakata, Sho [1 ]
机构
[1] Ehime Univ, Fac Engn, Matsuyama, Ehime 7908577, Japan
关键词
D O I
10.1002/pssc.200669599
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Polycrystalline Mg(x)Z(1-x)O (0.00 <= x <= 0.21) and ZnO:Mn films prepared by chemical spray pyrolysis were characterized by X-ray diffraction, optical transmittance, photoacoustic (PA) spectroscopy and photoluminescence (PL). Successful growth of the MgxZn1-xO (0.00 <= x <= 0.21) films was confirmed by the blue shift of both the near-band-edge PL peak and absorption edge with increasing the alloy composition x. However, the influence of the tail states caused by the deviation from stoichiometric compsosition and/or the spatial fluctuation of the alloy composition x was observed on the PA and PL spectra. Both the transmittance and PA spectra for the ZnO:Mn films showed the absorption band due to the d-d transitions in Mn2+ ion. (c) 2003 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:2677 / 2680
页数:4
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