Defect-rich MoS2(1-x)Se2x few-layer nanocomposites: a superior anode material for high-performance lithium-ion batteries

被引:40
|
作者
Cai, Guohui [1 ,2 ,3 ]
Peng, Lei [1 ,2 ,3 ]
Ye, Shiyong [1 ,2 ,3 ]
Huang, Yucheng [1 ,2 ,3 ]
Wang, Guangfeng [1 ,2 ,3 ]
Zhang, Xiaojun [1 ,2 ,3 ]
机构
[1] Key Lab Chem Biosensing, Wuhu, Anhui, Peoples R China
[2] Key Lab Funct Mol Solids, Wuhu, Anhui, Peoples R China
[3] Anhui Normal Univ, Coll Chem & Mat Sci, Wuhu 241000, Peoples R China
基金
中国国家自然科学基金;
关键词
MOS2 ULTRATHIN NANOSHEETS; ELECTROCHEMICAL PERFORMANCE; FREESTANDING ELECTRODE; GRAPHENE NANOSHEETS; HIERARCHICAL MOS2; STORAGE; SELENIUM; MOS2XSE2(1-X); INTERFACE; NANOWIRES;
D O I
10.1039/c8ta11583d
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Herein, defect-rich MoS2(1-x)Se2x few-layer nanocomposites were prepared by the co-etching method using molybdenum trioxide nanowires as a template. The novel defect-rich structure introduces additional active edge sites into the MoS2(1-x)Se2x few-layer nanocomposites; these additional active edge sites significantly improve the electrochemical energy storage performance of the few-layer nanocomposites; thus, MoS2(1-x)Se2x (x = 0.25) shows excellent electrochemical performance e.g. the specific capacity of up to 500 mA h g(-1) at the large current density of 5C after 350 cycles, and the coulombic efficiency is close to 100%. These excellent performances have proved that these few-layer ternary metal sulfide-selenide nanomaterials with rich defects can be widely used in Li-ion batteries.
引用
收藏
页码:9837 / 9843
页数:7
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